Contents of: VI/111/./abstract/CWRIGHT_CWRIGH_2.abs

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    Observations of molecular ices on interstellar dust grains
 can be used to constrain the physical conditions that were
 present when the ice first formed. This has already been done in
 a limited way using the 3.1 um stretching vibration of the most
 abundant ice, H_2O (Smith et al., 1989, ApJ 344, 413). However,
 the other vibrations of H_2O ice can also provide important and
 unique information. We are proposing to use the ISO Long
 Wavelength Spectrometer (LWS) to investigate two key problems
 relating to the formation of icy mantles and the nature of grain
 surfaces, by observing the far-infrared translational-mode
 spectrum of H_2O ice in a small, carefully selected sample of
 objects.
    The primary objective of this proposal is to measure the
 relative strengths of three of the translational mode features
 in the far-infrared spectrum of H_2O ice; these fall at 44 um,
 62 um and 165 um. The 44/62 um peak ratio is indicative of the
 formation conditions of the ice and can be used to trace the
 temperature history of the dust, e.g. whether it was initially
 deposited at low temperatures and then warmed up (as might
 occur when a protostar forms in a molecular cloud) or whether
 it was initially deposited at high temperatures and then cooled
 (as might occur in a circumstellar envelope). On the other
 hand, the strength or even the presence of the 165 um feature
 seems to be dependant on the nature of the grain surface.
    In conjunction with existing and ongoing laboratory work we
 can use the proposed observations to provide a powerful tool for
 studying the formation of icy grain mantles and the nature of
 the surfaces they were formed on.